Barangay Alfonso XII

Situated in Libacao, Aklan, Barangay Alfonso XII is one of 24 barangays that make up the municipality within Western Visayas.

According to the 2020 Census of Population and Housing conducted by the Philippine Statistics Authority, Barangay Alfonso XII had a population of 1,300. This made it the 9th largest of 24 barangays in Libacao by population, placing it in the middle tier of the municipality. Residents of Barangay Alfonso XII accounted for approximately 4.60% of the total population of Libacao, which stood at 28,272 in the same census year.

Census comparisons between 2015 and 2020 show Barangay Alfonso XII moving from 1,331 residents to 1,300 residents, an intercensal change of -2.3%. The trajectory indicates a contracting community. The Philippine Statistics Authority classifies Barangay Alfonso XII as rural, a designation applied to barangays with lower population density and predominantly non-built-up land use.

Libacao is a municipality comprising 24 barangays, and serves as the governing unit directly responsible for local services in Barangay Alfonso XII, including public health, sanitation, peace and order, and civil registration. Within the wider province of Aklan, which contains 327 barangays across its component cities and municipalities, Barangay Alfonso XII ranks 177th by 2020 population. Aklan is classified as a 2nd by the Bureau of Local Government Finance, a category that reflects the province's annual regular income.

The barangay's legislative and executive affairs are handled by a Punong Barangay and the Sangguniang Barangay, elected nationwide during the Barangay and SK Elections. The next BSKE is scheduled for Monday, November 2, 2026, following the synchronized election schedule set by COMELEC Resolution No. 11191.